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Article #241: Have You Selected Wrong Materials for Chemicals?

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Chemicals are very much a part of our to be compatible to these chemicals. If
lifestyles. Every household detergent, the wrong material is selected, it can
solvent, and bleach that you use in your lead to dangerous and widespread
homes is a result of some production consequences of chemical spills,
efforts from manufacturing plants emergency evacuation, pollution,
somewhere in the world around you. environmental damage and other
Fertilizer, automobile radiator coolant, disruptions to the production facility.
shampoo, soap, insecticide, paint Engineers in such chemical processing
solvent, lubricants, fuel oil are just a plants need to know what materials are
few that I can name right now. I'm sure suitable to be used for their process. It
you can find more around you, but you get is much more complex than just selecting
the point. We use chemicals everywhere. materials for water pumps. Much detailed
Anyone who has visited a chemical and careful selection choices based on
processing plant is sure to notice the the chemicals, the temperatures (because
many pumps, agitators, tanks, piping, and some of the plastic materials can weaken
valves that are installed there. Liquid at temperatures that are considered
have to be transferred from one place to normal for metals), chemical reactions,
another. Pumps are therefore very safety, spills and many others have to be
important in a chemical processing plant. taken.
Without them the chemical processing The aim of any maintenance personnel is
plant will literarily come to a halt! to lengthen the lifespan of equipment
One of the main jobs for Plant Engineers under his care. Selection of chemical
is to maintain the numerous pumps resistant materials is not a
installed at their plant. These pumps can one-cure-fits-all solution. Some
count into the hundreds or even materials are not affected by certain
thousands, depending on the size of the chemicals but can be damaged by others.
plant. So you should realize that to do a Some have good mechanical strength while
proper preventive maintenance, it is no others cannot last long without
mean task. There must be regular reinforcement. Usually, materials that
schedules, proper tracking of jobs done, can withstand many types of chemicals are
available manpower and skills, suitable very expensive.
tools, replacement parts, materials and a Cost considerations need to be taken into
proper system of administration of all account when choosing a material for a
these. certain application. If there is a choice
Sometimes, even with all the maintenance of materials for a certain application,
activities being carried out, pumps do it makes better sense to choose cheaper
fail. And when they do, plant engineers materials if they can perform just as
will have to find out what causes them to well.
fail. Especially with new pumps where There are several components to check for
there is very little record trend of when selecting suitable materials:
breakdown, engineers will be hard pressed 1) Elastomers for flexible parts like
into finding solutions for this. This is seal rings and gaskets
when experience helps in pinpointing the 2) Metal parts like shafting, springs,
cause(s) of the failure. holders, bolts & nuts, and pressure
Pumps or other machinery will give gauges
tell-tale signs when they are not working 3) Plastic parts like housing, piping,
properly. An observant pump user will be impellers, and covers
able to avoid major breakdowns or damage Metals have good mechanical strength that
if the problem is corrected early. can last very long in operation. In fact
In order to solve any pump problem, we some parts need to be made of metal, e.g.
need to notice the symptoms carefully so bearing housing and shafts. Pump housing
as to determine the most likely causes. made of metal can be casted and machined
Instruments like pressure gauges are very easily. They are able to withstand
helpful and should be installed in the abrasive fluids and rough handling
pumping system. without any other reinforcement. One very
Very often we do have to rely on our 5 important characteristic of metals is
senses to determine the exact symptom. heat conduction. If the chemical to be
Normally, pump problems can be classified pumped is hot, metal is always the
into: choice.
1) Suction Related, Plastics have become the better choice
2) System Related, or for many corrosive chemical applications
3) Mechanical Related. because it is more resistant to chemical
It can also be a combination of these. action than metals. When using plastics
Most of the system related problems occur to replace metals, you have to compromise
because of design flaw. For example, the on the mechanical strength of the pump.
designer may have chosen the wrong pump If the pump does not encounter much rough
whose characteristic does not match the handling or abrasion, plastics can be
system requirement. Suction related used. Sometimes plastics are used to coat
problems are usually caused by air locks metal parts. These are fine as long as
that are due to a variety of reasons. I the plastic coating remains intact.
will not mention them here. Elastomers are the flexible materials
The effects of mechanical related that are needed for sealing the pump
problems could manifest themselves as parts. There should not be any compromise
suction related problems - air leaks in here. Laboratory tests on the suitability
the system, worn out impellers, and mouth of elastomers with certain chemicals
rings - but the most common symptom is should be followed. Unsuitable material
the presence of vibration and abnormal used can cause leaks that can lead to
noise in the equipment. other failures in other parts.
However, there is one area where we With so many chemicals in use today, how
seldom focus on - the effect of do we know what materials can be used for
chemicals. Was the material selected able what chemicals? Sometimes liquids to be
to withstand the chemicals? If you have pumped contain chemicals that are both
done all your designing right and you corrosive and abrasive. Should we choose
still find that leaks are occurring so a plastic or a metal housing? Sometimes
frequently, chances are that the chemicals may become hot either through
materials are failing due to chemical the process or through mis-operation of
reaction. Signs of corrosion at the seals the system - perhaps, somebody forgot to
are a strong indication of material open a valve. Plastic parts can weaken at
failure due to wrong usage. high temperatures.
Nowadays, waste treatment plants or even It's only through the result of test and
process plants are called upon to process actual operation that we are able to know
strong acids, alkalis, oxidizers, what materials to use. It is good to know
solvents, waste, slurry and other what to expect when we make a decision
corrosive and abrasive chemicals. And it for a choice of materials to use. A good
is not only pumps that are affected. choice may involve some compromise.
Agitators, storage tanks, and piping need






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