Have You Selected Wrong Materials for Chemicals?

Chemicals are very much a part of our lifestyles.selected, it can lead to dangerous and widespread
Every household detergent, solvent, and bleachconsequences of chemical spills, emergency
that you use in your homes is a result of someevacuation, pollution, environmental damage and
production efforts from manufacturing plantsother disruptions to the production facility.
somewhere in the world around you. Fertilizer,Engineers in such chemical processing plants need
automobile radiator coolant, shampoo, soap,to know what materials are suitable to be used
insecticide, paint solvent, lubricants, fuel oil are justfor their process. It is much more complex than
a few that I can name right now. I'm sure youjust selecting materials for water pumps. Much
can find more around you, but you get the point.detailed and careful selection choices based on the
We use chemicals everywhere.chemicals, the temperatures (because some of
Anyone who has visited a chemical processingthe plastic materials can weaken at temperatures
plant is sure to notice the many pumps, agitators,that are considered normal for metals), chemical
tanks, piping, and valves that are installed there.reactions, safety, spills and many others have to
Liquid have to be transferred from one place tobe taken.
another. Pumps are therefore very important in aThe aim of any maintenance personnel is to
chemical processing plant. Without them thelengthen the lifespan of equipment under his care.
chemical processing plant will literarily come to aSelection of chemical resistant materials is not a
halt!one-cure-fits-all solution. Some materials are not
One of the main jobs for Plant Engineers is toaffected by certain chemicals but can be
maintain the numerous pumps installed at theirdamaged by others. Some have good mechanical
plant. These pumps can count into the hundredsstrength while others cannot last long without
or even thousands, depending on the size of thereinforcement. Usually, materials that can
plant. So you should realize that to do a properwithstand many types of chemicals are very
preventive maintenance, it is no mean task. Thereexpensive.
must be regular schedules, proper tracking ofCost considerations need to be taken into account
jobs done, available manpower and skills, suitablewhen choosing a material for a certain application.
tools, replacement parts, materials and a properIf there is a choice of materials for a certain
system of administration of all these.application, it makes better sense to choose
Sometimes, even with all the maintenancecheaper materials if they can perform just as
activities being carried out, pumps do fail. Andwell.
when they do, plant engineers will have to findThere are several components to check for
out what causes them to fail. Especially with newwhen selecting suitable materials:
pumps where there is very little record trend of1) Elastomers for flexible parts like seal rings and
breakdown, engineers will be hard pressed intogaskets
finding solutions for this. This is when experience2) Metal parts like shafting, springs, holders, bolts
helps in pinpointing the cause(s) of the failure.& nuts, and pressure gauges
Pumps or other machinery will give tell-tale signs3) Plastic parts like housing, piping, impellers, and
when they are not working properly. Ancovers
observant pump user will be able to avoid majorMetals have good mechanical strength that can
breakdowns or damage if the problem islast very long in operation. In fact some parts
corrected early.need to be made of metal, e.g. bearing housing
In order to solve any pump problem, we need toand shafts. Pump housing made of metal can be
notice the symptoms carefully so as to determinecasted and machined easily. They are able to
the most likely causes. Instruments like pressurewithstand abrasive fluids and rough handling
gauges are very helpful and should be installed inwithout any other reinforcement. One very
the pumping system.important characteristic of metals is heat
Very often we do have to rely on our 5 sensesconduction. If the chemical to be pumped is hot,
to determine the exact symptom. Normally, pumpmetal is always the choice.
problems can be classified into:Plastics have become the better choice for many
1) Suction Related,corrosive chemical applications because it is more
2) System Related, orresistant to chemical action than metals. When
3) Mechanical Related.using plastics to replace metals, you have to
It can also be a combination of these.compromise on the mechanical strength of the
Most of the system related problems occurpump. If the pump does not encounter much
because of design flaw. For example, the designerrough handling or abrasion, plastics can be used.
may have chosen the wrong pump whoseSometimes plastics are used to coat metal parts.
characteristic does not match the systemThese are fine as long as the plastic coating
requirement. Suction related problems are usuallyremains intact.
caused by air locks that are due to a variety ofElastomers are the flexible materials that are
reasons. I will not mention them here.needed for sealing the pump parts. There should
The effects of mechanical related problems couldnot be any compromise here. Laboratory tests on
manifest themselves as suction related problems -the suitability of elastomers with certain chemicals
air leaks in the system, worn out impellers, andshould be followed. Unsuitable material used can
mouth rings - but the most common symptom iscause leaks that can lead to other failures in other
the presence of vibration and abnormal noise inparts.
the equipment.With so many chemicals in use today, how do we
However, there is one area where we seldomknow what materials can be used for what
focus on - the effect of chemicals. Was thechemicals? Sometimes liquids to be pumped
material selected able to withstand the chemicals?contain chemicals that are both corrosive and
If you have done all your designing right and youabrasive. Should we choose a plastic or a metal
still find that leaks are occurring so frequently,housing? Sometimes chemicals may become hot
chances are that the materials are failing due toeither through the process or through
chemical reaction. Signs of corrosion at the sealsmis-operation of the system - perhaps,
are a strong indication of material failure due tosomebody forgot to open a valve. Plastic parts
wrong usage.can weaken at high temperatures.
Nowadays, waste treatment plants or evenIt's only through the result of test and actual
process plants are called upon to process strongoperation that we are able to know what
acids, alkalis, oxidizers, solvents, waste, slurry andmaterials to use. It is good to know what to
other corrosive and abrasive chemicals. And it isexpect when we make a decision for a choice of
not only pumps that are affected. Agitators,materials to use. A good choice may involve
storage tanks, and piping need to be compatiblesome compromise.
to these chemicals. If the wrong material is